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从烯基烷氧基五配位的铬卡宾配合物和炔烃合成cr(co)3配位的氢醌。


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反应机理


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反应实例






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参考文献


1. dötz, k. h. angew. chem. 1975, 87, 672-673.

2. dötz, k. h. angew. chem., int. ed. engl. 1975, 14,644-645.

3. dötz, k. h. angew. chem. 1979, 91, 1021-1022.

4. dötz, k. h., chem. ber. 1980, 113, 1449-1457.

5. casey, c. p. metal-carbene complexes [as reactiveintermediates]. reactive intermediates (wiley) 1981, 2, 135-174.

6. tang, p. c., wulff, w. d. j. am. chem. soc. 1984, 106,1132-1133.

7. merlic, c. a., aldrich, c. c., albaneze-walker, j.,saghatelian, a., mammen, j. j. org. chem. 2001, 66, 1297-1309.

8. king, j., quayle, p., malone, j. f. tetrahedron lett.1990, 31, 5221-5224.

9. pulley, s. r., carey, j. p. j. org. chem.1998, 63,5275-5279.


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